Zakon o potvrđivanju Odluke 2014/2 o izmeni Aneksa I Konvencije o…

Član 2

(1) Tekst Odluke 2014/2 o izmeni Aneksa I Konvencije o prekograničnim efektima industrijskih udesa, u originalu na engleskom jeziku i u prevodu na srpski jezik glasi:

(2) Decision 2014/2

(3) Amending annex I to the Convention

(4) The Conference of the Parties,

(5) Recognizing the need to update the categories of substances and mixtures and the named substances and their threshold quantities, as contained in annex I to the Convention on the Transboundary Effects of Industrial Accidents, for the purposes of introducing the criteria of the United Nations Globally Harmonized System of Classification and Labelling of Chemicals (ST/SG/AC.10/30/Rev.4) and of maintaining consistency with the corresponding European Union legislation,

(6) Bearing in mind its decision to undertake a revision of the hazardous substances and their quantities as contained in annex I, and its decision 2004/4 on establishing the Working Group on the Development of the Convention,

(7) Acknowledging the proposal to amend annex I, drawn up by the Working Group on the basis of a thorough review,

(8) Amends annex I to the Convention on hazardous substances for the purposes of defining hazardous activities by replacing it with the text set out in the annex to this decision.

(9) Annex I

(10) Hazardous substances for the purposes of defining hazardous activities1

(11) Where a substance or mixture named in Part II also falls within one or more categories in Part I, the threshold quantity given in Part II shall be used.

(12) For the identification of hazardous activities, Parties shall take into consideration the actual or anticipated hazardous properties and/or quantities of all hazardous substances present or of hazardous substances which it is reasonable to foresee may be generated during loss of control of an activity, including storage activities, within a hazardous activity.

(13) Part I.

(14) Categories of substances and mixtures not specifically named in Part II

(15) Category in accordance with the United Nations Globally Harmonized System (GHS) of Classification and Labelling of Chemicals

(16) Treshold quantity

(17) (metric tons)

(18) 1.

(19) Acute toxic, Category 1, all exposure routes2

(20) 20

(21) 2.

(22) Acute toxic: Category 2, all exposure routes3 Category 3, inhalation exposure route4

(23) 200

(24) 3.

(25) Specific Target Organ Toxicity (STOT) – Single Exposure (SE) STOT, Category 15

(26) 200

(27) 4.

(28) Explosives – unstable explosives or explosives, where the substance, mixture or article falls under division 1.1, 1.2, 1.3, 1.5 or 1.6 of chapter 2.1.2. of the GHS criteria or substances or mixtures having explosive properties according to Test series 2 of Part I of the United Nations Recomendations on the Transport of Dangerous Goods: Manual of Test and Criteria (Manual of Test and Criteria) and do not belong to the hazard classes Organic peroxides or Self-reactive substances and mixtures6,7

(29) 50

(30) 5.

(31) Explosives, where the substance, mixture or article falls under division 1.4 of chapter 2.1.2 of the GHS7,8

(32) 200

(33) 6.

(34) Flammable gases, Category 1 or 29

(35) 50

(36) 7.

(37) Aerosols,10 Category 1 or 2, containing flammable gases Category 1 or 2 or flammable liquids Category 1

(38) 500 (net)

(39) 8.

(40) Aerosols,10 Category 1 or 2, not containing flammable gases Category 1 or 2 nor flammable liquids Category 111

(41) 50 000 (net)

(42) 9.

(43) Oxidizing gases, Category 112

(44) 200

(45) 10.

(46) Flammable liquids:

(47) Flammable liquids, Category 1, or

(48) Flammable liquids Category 2 or 3, maintained at a temperature above their boiling point,13 or

(49) Other liquids with a flash point ≤ 60 °C, maintained at a temperature above their boiling point14

(50) 50

(51) 11.

(52) Flammable liquids:

(53) Flammable liquids Category 2 or 3 where particular processing conditions, such as high pressure or high temperature, may create industrial accident hazards,15 or

(54) Other liquids with a flash point ≤ 60 °C where particular processing conditions, such as high pressure or high temperature, may create industrial accident hazards14

(55) 200

(56) 12.

(57) Flammable liquids, Categories 2 or 3, not covered by 10 and 1116

(58) 50 000

(59) 13.

(60) Self-reactive substances and mixtures and organic peroxides: Self-reactive substances and mixtures, Type A or B, or Organic peroxides, Type A or B17

(61) 50

(62) 14.

(63) Self-reactive substances and mixtures and organic peroxides: Self-reactive substances and mixtures, Type C,D,E or F, or Organic peroxides, Type C,D,E, or F18

(64) 200

(65) 15.

(66) Pyrophoric liquids and solids, Category 1

(67) 200

(68) 16.

(69) Oxidizing liquids and solids, Category 1, 2 or 3

(70) 200

(71) 17.

(72) Hazardous to the aquatic environment, Category Acute 1 or Chronic 119

(73) 200

(74) 18.

(75) Hazardous to the aquatic environment, Category Chronic 220

(76) 500

(77) 19.

(78) Substances and mixtures which react violently with water, such as acetyl chloride, titanium tetrachloride

(79) 500

(80) 20.

(81) Substances and mixtures which in contact with water emit flammable gases, Category 121

(82) 500

(83) 21.

(84) Substances and mixtures which in contact with water liberate toxic gas (substances and mixtures wich in contact with water or damp air evolve gases classified for acute toxicity in category 1,2 or 3, such as aluminium phosphide or phosphorous pentasulphide)

(85) 200

(86) Part II.

(87) Named substances

(88) Substance

(89) Treshold quantity

(90) (metric tons)

(91) 1a.

(92) Ammonium nitrate22

(93) 10 000

(94) 1b.

(95) Ammonium nitrate23

(96) 5 000

(97) 1c.

(98) Ammonium nitrate24

(99) 2 500

(100) 1d.

(101) Ammonium nitrate25

(102) 50

(103) 2a.

(104) Potassium nitrate26

(105) 10 000

(106) 2b.

(107) Potassium nitrate27

(108) 5 000

(109) 3.

(110) Arsenic pentoxide, arsenic (V) acid and/or salts

(111) 2

(112) 4.

(113) Arsenic trioxide, arsenious (III) acid and/or salts

(114) 0.1

(115) 5.

(116) Bromine

(117) 100

(118) 6.

(119) Chlorine

(120) 25

(121) 7.

(122) Nickel compounds in inhalable powder form: nickel monoxide, nickel dioxide, nickel sulphide, trinickel disulphide, dinickel trioxide

(123) 1

(124) 8.

(125) Ethyleneimine

(126) 20

(127) 9.

(128) Fluorine

(129) 20

(130) 10.

(131) Formaldehyde (concentration ≥ 90%)

(132) 50

(133) 11.

(134) Hydrogen

(135) 50

(136) 12.

(137) Hydrogen chloride (liquefied gas)

(138) 250

(139) 13.

(140) Lead alkyls

(141) 50

(142) 14.

(143) Liquefied flammable gases, Category 1 or 2 (including liquefied petroleum gas) and natural gas28

(144) 200

(145) 15.

(146) Acetylene

(147) 50

(148) 16.

(149) Ethylene oxide

(150) 50

(151) 17.

(152) Propylene oxide

(153) 50

(154) 18.

(155) Methanol

(156) 5 000

(157) 19.

(158) 4, 4′-Methylene bis (2-chloraniline) and/or salts, in powder form

(159) 0.01

(160) 20.

(161) Methylisocyanate

(162) 0.15

(163) 21.

(164) Oxygen

(165) 2 000

(166) 22.

(167) Toluene diisocyanate (2,4 -Toluene diisocyanate and 2,6 -Toluene diisocyanate

(168) 100

(169) 23.

(170) Carbonyl dichloride (phosgene)

(171) 0.75

(172) 24.

(173) Arsine (arsenic trihydride)

(174) 1

(175) 25.

(176) Phosphine (phosphorus trihydride)

(177) 1

(178) 26.

(179) Sulphur dichloride

(180) 1

(181) 27.

(182) Sulphur trioxide

(183) 75

(184) 28.

(185) Polychlorodibenzofurans and polychlorodibenzodioxins (including tetrachlorodibenzodioksin (TCDD)), calculated in TCDD equivalent29

(186) 0.001

(187) 29.

(188) The following carcinogens or the mixtures containing the following carcinogens at concentrations above 5% by weight: 4-Aminobiphenyl and/or its salts, Benzotrichloride, Benzidine and/or salts, Bis (chloromethyl) ether, Chloromethyl methyl ether, 1,2-Dibromoethane, Diethyl sulphate, Dimethyl sulphate, Dimethylcarbamoyl chloride, 1,2-Dibromo-3-chloropropane, 1,2-Dimethylhydrazine, Dimethylnitrosamine, Hexamethylphosphoric triamide, Hydrazine, 2- Naphthylamine and/or salts, 4-Nitrodiphenyl, and 1,3 Propanesultone

(189) 2

(190) 30.

(191) Petroleum products and alternative fuels: (a) Gasolines and naphthas; (b) Kerosenes (including jet fuels); (c) Gas oils (including diesel fuels, home heating oils and gas oil blending streams); (d) Heavy fuel oils; (e) Alternative fuels serving the same purposes and with similar properties as regards flammability and environmental hazards as the products referred to in points (a) to (d)

(192) 25 000

(193) 31.

(194) Anhydrous ammonia

(195) 200

(196) 32.

(197) Boron trifluoride

(198) 20

(199) 33.

(200) Hydrogen sulphide

(201) 20

(202) 34.

(203) Piperidine

(204) 200

(205) 35.

(206) Bis(2-dimethylaminoethyl) (methyl)amin

(207) 200

(208) 36.

(209) 3-(2-Ethylhexyloxy)propylamin

(210) 200

(211) 37.

(212) Mixtures of sodium hypochlorite classified as Aquatic Acute Category 1 [H400] containing < than 5% active chlorine and not classified under any of the other hazard categories in Part 1 of annex I.30

(213) 500

(214) 38.

(215) Propylamine31

(216) 2 000

(217) 39.

(218) Tert-butyl acrylate31

(219) 500

(220) 40.

(221) 2-Methyl-3-butenenitrile31

(222) 2 000

(223) 41.

(224) Tetrahydro-3,5-dimethyl-1,3,5,-thiadiazine-2-thione (dazomet)31

(225) 200

(226) 42.

(227) Methyl acrylate31

(228) 2 000

(229) 43.

(230) 3-Methylpyridine31

(231) 2 000

(232) 44.

(233) 1-Bromo-3-chloropropane31

(234) 2 000

(235) Notes

(236) 1Criteria according the United Nations Globally Harmonized System (GHS) of Classification and Labelling of Chemicals (ST/SG/AC.10/30/Rev.4). Parties should use these criteria when classifying substances or mixtures for the purposes of Part I of this annex, unless other legally binding criteria have been adopted in the national legislation. Mixtures shall be treated in the same way as the pure substance, provided they remain within concentration limits set according to their properties in accordance with the GHS unless a percentage composition or other description is specifically given.

(237) 2According to the criteria in chapters 3.1.2 and 3.1.3 of GHS.

(238) 3According to the criteria in chapters 3.1.2 and 3.1.3 of GHS.

(239) 4Substances that fall within acute toxic Category 3 via the oral route shall fall under entry 2 acute toxic in those cases where neither acute inhalation toxicity classification nor acute dermal toxicity classification can be derived, for example due to lack of conclusive inhalation and dermal toxicity data.

(240) 5Substances that have produced significant toxicity in humans, or that, on the basis of evidence from studies in experimental animals can be presumed to have the potential to produce significant toxicity in humans following single exposure. Further guidance is given in figure 3.8.1. and table 3.8.1 of part 3 of GHS.

(241) 6Testing for explosive properties of substances and mixtures is only necessary if the screening procedure according to appendix 6, part 3, of the Manual of Tests and Criteria identifies the substance or mixture as potentially having explosive properties.

(242) 7The hazard class Explosives includes explosive articles. If the quantity of the explosive substance or mixture contained in the article is known, that quantity shall be considered for the purposes of this Convention. If the quantity of the explosive substance or mixture contained in the article is not known, then, for the purposes of this Convention, the whole article shall be treated as explosive.

(243) 8If Explosives of division 1.4 are unpacked or repacked, they shall be assigned to the entry 4 (Explosive), unless the hazard is shown to still correspond to division 1.4, in accordance with GHS.

(244) 9According to the criteria in chapter 2.2.2 of GHS.

(245) 10Aerosols are classified according to the criteria in chapter 2.3 of GHS and the Manual of Tests and Criteria, Part III, section 31 referred to therein.

(246) 11In order to use this entry, it must be documented that the aerosol dispenser does not contain flammable gas Category 1 or 2 nor flammable liquid Category 1.

(247) 12According to the criteria in chapter 2.4.2 of GHS.

(248) 13According to the criteria in chapter 2.6.2 of GHS.

(249) 14Liquids with a flash point of more than 35°C may be regarded as non-flammable liquids for some regulatory purposes (e.g., transport) if negative results have been obtained in sustained combustibility test L.2, in part III, section 32 of the Manual of Tests and Criteria. This is, however, not valid under elevated conditions such as high temperature or pressure, and therefore such liquids are included in this entry.

(250) 15According to the criteria in chapter 2.6.2 of GHS.

(251) 16According to the criteria in chapter 2.6.2 of GHS.

(252) 17According to the criteria in chapters 2.8.2 and 2.15.2.2 of GHS.

(253) 18According to the criteria in chapters 2.8.2 and 2.15.2.2 of GHS.

(254) 19According to the criteria in chapter 4.1.2 of GHS.

(255) 20According to the criteria in chapter 4.1.2 of GHS.

(256) 21According to the criteria in chapter 2.12.2 of GHS.

(257) 22Ammonium nitrate (10,000): fertilizers capable of self-sustaining decomposition.

(258) This applies to ammonium nitrate–based compound/composite fertilizers (compound/composite fertilizers containing ammonium nitrate with phosphate and/or potash), which are capable of self-sustaining decomposition according to the Trough Test (see Manual of Tests and Criteria, part III, subsection 38.2), and in which the nitrogen content as a result of ammonium nitrate is:

(259) (a) Between 15.75% and 24.5% by weight (15.75% and 24.5% nitrogen content by weight as a result of ammonium nitrate correspond to 45% and 70% ammonium nitrate, respectively) and which either contain not more than 0.4% total combustible/organic materials or fulfil the requirements of an appropriate test of resistance to detonation (e.g., 4- inch-steel-tube test);

(260) (b) 15.75% by weight or less and unrestricted combustible materials.

(261) 23Ammonium nitrate (5,000): fertilizer grade.

(262) This applies to straight ammonium nitrate-based fertilizers and to ammonium nitrate-based compound/composite fertilizers in which the nitrogen content as a result of ammonium nitrate is:

(263) (a) More than 24.5% by weight, except for mixtures of straight ammonium nitrate-based fertilizers with dolomite, limestone and/or calcium carbonate with a purity of at least 90%;

(264) (b) More than 15.75% by weight for mixtures of ammonium nitrate and ammonium sulphate;

(265) (c) More than 28% (28% nitrogen content by weight as a result of ammonium nitrate corresponds to 80% ammonium nitrate) by weight for mixtures of straight ammonium nitrate-based fertilizers with dolomite, limestone and/or calcium carbonate with a purity of at least 90%;

(266) and which fulfil the requirements of an appropriate test of resistance to detonation (e.g., 4-inch-steel-tube test).

(267) 24Ammonium nitrate (2,500): technical grade.

(268) This applies to:

(269) (a) Ammonium nitrate and mixtures of ammonium nitrate in which the nitrogen content as a result of ammonium nitrate is:

(270) (i) Between 24.5% and 28% by weight and which contain not more than 0.4% combustible substances;

(271) (ii) More than 28% by weight, and which contain not more than 0.2% combustible substances;

(272) (b) Aqueous ammonium nitrate solutions in which the concentration of ammonium nitrate is more than 80% by weight.

(273) 25Ammonium nitrate (50): “off-specs” material and fertilizers not fulfilling the requirements of an appropriate test of resistance to detonation (e.g., 4-inch-steel-tube test).

(274) This applies to:

(275) (a) Material rejected during the manufacturing process and to ammonium nitrate and mixtures of ammonium nitrate, straight ammonium nitrate-based fertilizers and ammonium nitrate-based compound/composite fertilizers referred to in notes 23 and 24 that are being or have been returned from the final user to a manufacturer, temporary storage or reprocessing plant for reworking, recycling or treatment for safe use because they no longer comply with the specifications in notes 23 and 24;

(276) (b) Fertilizers referred to in note 22 (a) and note 23 which do not fulfil the requirements of an appropriate test of resistance to detonation (e.g., 4-inch-steel-tube test).

(277) 26Potassium nitrate (10,000): composite potassium nitrate-based fertilizers (in prilled/granular form) which have the same properties as pure potassium nitrate.

(278) 27Potassium nitrate (5,000): composite potassium nitrate-based fertilizers (in crystalline form) which have the same hazardous properties as pure potassium nitrate.

(279) 28Upgraded biogas: for the purpose of the implementation of the Convention, upgraded biogas may be classified under entry 14 of Part 2 of annex I where it has been processed in accordance with applicable standards for purified and upgraded biogas ensuring a quality equivalent to that of natural gas, including the content of methane, and which has a maximum of 1% oxygen.

(280) 29Polychlorodibenzofurans and polychlorodibenzodioxins. The quantities of polychlorodibenzofurans and polychlorodibenzodioxins are calculated using the following World Health Organization (WHO) human and mammalian toxic equivalency factors (TEF) for dioxins and dioxin-like compounds as reevaluated in 2005:

(281) WHO 2005 TEF

(282) Dioxins

(283) TEF

(284) Furans

(285) TEF

(286) 2,3,7,8-TCDD

(287) 1

(288) 2,3,7,8-TCDF

(289) 0.1

(290) 1,2,3,7,8-PeCDD

(291) 1

(292) 2,3,4,7,8-PeCDF

(293) 0.3

(294) 1,2,3,4,7,8-HxCDD

(295) 0.1

(296) 1,2,3,7,8-PeCDF

(297) 0.03

(298) 1,2,3,6,7,8-HxCDD

(299) 0.1

(300) 1,2,3,4,7,8-HxCDF

(301) 0.1

(302) 1,2,3,7,8,9-HxCDD

(303) 0.1

(304) 1,2,3,7,8,9-HxCDF

(305) 0.1

(306) 1,2,3,4,6,7,8-HpCDD

(307) 0.01

(308) 2,3,4,6,7,8-HxCDF

(309) 0.1

(310) OCDD

(311) 0.0003

(312) 1,2,3,7,8,9-HxCDF

(313) 0.1

(314) 1,2,3,4,6,7,8-HpCDF

(315) 0.01

(316) 1,2,3,4,7,8,9-HpCDF

(317) 0.01

(318) OCDF

(319) 0.0003

(320) Abbreviations: Hx = hexa, Hp = hepta, O = octa, Pe = penta, T = tetra.

(321) Reference: Martin Van den Berg and others, “The 2005 World Health Organization

(322) Reevaluation of Human and Mammalian Toxic Equivalency Factors for Dioxins and Dioxin-like Compounds”, Toxicological Sciences, vol. 93, No. 2 (October 2006), pp. 223–241.

(323) 30Provided that the mixture in the absence of sodium hypochlorite would not be classified as aquatic acute, Category 1.

(324) 31In cases where this dangerous substance falls within the category 10 flammable liquids or category 11 flammable liquids, for the purposes of the Convention the lowest qualifying quantities shall apply.

(325) Odluka 2014/2

(326) O izmeni Aneksa I Konvencije

(327) Konferencija Strana,

(328) Prepoznajući potrebu da se ažuriraju kategorije supstanci i smeša i navedene supstance i njihove granične količine, kako je sadržano u Aneksu I Konvencije o prekograničnim efektima industrijskih udesa, u cilju uvođenja kriterijuma Globalno harmonizovanog sistema klasifikacije i obeležavanja hemikalija Ujedinjenih nacija (ST/SG/AC.10/30/Rev.4) i održavanja doslednosti sa odgovarajućim zakonodavstvom Evropske unije,

(329) Imajući u vidu svoju odluku da se izvrši revizija opasnih supstanci i njihovih količina iz Aneksa I, i svoju odluku 2004/4 o uspostavljanju Radne grupe za razvoj konvencije,

(330) Uvažavajući predlog da se izmeni Aneks I, koji je izradila radna grupa na osnovu detaljnog razmatranja,

(331) Menja Aneks I Konvencije o opasnim supstancama za potrebe definisanja opasnih aktivnosti zamenjujući je tekstom navedenim u Aneksu ove odluke.

(332) Aneks I

(333) Opasne supstance za potrebe definisanja opasnih aktivnosti1

(334) Kada supstanca ili smeša navedena u Delu II takođe spada u jednu ili više kategorija iz Dela I, koristi se granična količina data u Delu II.

(335) Za identifikaciju opasnih aktivnosti, Strane će uzeti u obzir stvarna ili očekivana opasna svojstva i/ili količine svih prisutnih opasnih supstanci ili opasnih supstanci za koje je razumno predvideti da mogu nastati tokom gubitka kontrole aktivnosti, uključujući aktivnosti skladištenja, u okviru opasne aktivnosti.

(336) Deo I

(337) Kategorije supstanci i smeša koje nisu posebno navedene i Delu II

(338) Kategorije u skladu sa Globalno harmonizovanim sistemom klasifikacije i obeležavanja hemikalija Ujedinjenih nacija (GHS)

(339) Granične količine (u tonama)

(340) 1.

(341) Akutna toksičnost, kategorija 1, svi putevi izlaganja2

(342) 20

(343) 2.

(344) Akutna toksičnost: Kategorija 2, svi putevi izlaganja3 Kategorija 3, inhalaciono4

(345) 200

(346) 3.

(347) Specifična toksičnost za ciljni organizam (STOT) – jednokratna izloženost (SE) STOT, kategorija 15

(348) 200

(349) 4.

(350) Eksplozivi – nestabilni eksplozivi ili eksplozivi, gde supstanca, smeša ili proizvod pripadaju podklasi 1.1, 1.2, 1.3, 1.5 ili 1.6 iz poglavlja 2.1.2. GHS kriterijuma ili supstance ili smeše koje imaju eksplozivna svojstva prema Testu serije 2 Dela I Preporuka Ujedinjenih nacija o transportu opasnog tereta: Priručnik o metodama ispitivanja i kriterijumima (Priručnik o metodama ispitivanja i kriterijumima) i koje ne pripadaju klasi opasnosti organski peroksidi ili samoreaktivne supstance ili smeše6,7

(351) 50

(352) 5.

(353) Eksplozivi, gde supstanca, smeša ili proizvod pripadaju podklasi 1.4 iz poglavlja 2.1.2 GHS7,8

(354) 200

(355) 6.

(356) Zapaljivi gasovi, kategorija 1 ili 29

(357) 50

(358) 7.

(359) Aerosoli,10 kategorije 1 ili 2, koji sadrže zapaljive gasove kategorije 1 ili 2 ili zapaljive tečnosti kategorije 1

(360) 500 (neto)

(361) 8.

(362) Aerosoli,10 kategorije 1 ili 2, koji ne sadrže zapaljive gasove kategorije 1 ili 2 niti zapaljive tečnosti kategorije 111

(363) 50 000 (neto)

(364) 9.

(365) Oksidujući gasovi, kategorija 112

(366) 200

(367) 10.

(368) Zapaljive tečnosti: Zapaljive tečnosti, kategorija 1, ili Zapaljive tečnosti kategorija 2 ili 3, koje se održavaju na temperaturi većoj od njihove tačke ključanja13, ili druge tečnosti čija je tačka paljenja ≤ 60 °C, koje se održavaju na temperaturi većoj od njihove tačke ključanja 14

(369) 50

(370) 11.

(371) Zapaljive tečnosti: Zapaljive tečnosti kategorije 2 ili 3 kod kojih posebni uslovi procesa, kao što su visok pritisak ili visoka temepratura, mogu stvoriti opasnosti od industrijskog udesa15, ili druge tečnosti sa tačkom paljenja ≤ 60 °C kod kojih posebni uslovi procesa, kao što su visok pritisak ili visoka temepratura, mogu stvoriti opasnosti od industrijskog udesa 14

(372) 200

(373) 12.

(374) Zapaljive tečnosti, kategorije 2 ili 3, koje nisu obuhvaćene pod 10. i 11.16

(375) 50 000

(376) 13.

(377) Samoreaktivne supstance i smeše i organski peroksidi: Samoreaktivne supstance i smeše, tip A ili B, ili Organski peroksidi, tip A ili B17

(378) 50

(379) 14.

(380) Samoreaktivne supstance i smeše i organski peroksidi: Samoreaktivne supstance i smeše, tip C, D ,E ili F, ili Organski peroksidi, tip C, D, E ili F18

(381) 200

(382) 15.

(383) Samozapaljive tečnosti i čvrste supstance, kategorija 1

(384) 200

(385) 16.

(386) Oksidujuće tečnosti i čvrste supstance, kategorije 1, 2 ili 3

(387) 200

(388) 17.

(389) Opasnost po vodenu životnu sredinu, kategorija Akutno 1 ili Hronično 119

(390) 200

(391) 18.

(392) Opasnost po vodenu životnu sredinu, kategorija Hronično 220

(393) 500

(394) 19.

(395) Supstance ili smeše koje burno reaguju sa vodom, kao što su acetil hlorid, titanijum tetrahlorid

(396) 500

(397) 20.

(398) Supstance i smeše koje u kontaktu sa vodom oslobađaju zapaljive gasove, kategorija 121

(399) 500

(400) 21.

(401) Supstance i smeše koje u kontaktu sa vodom oslobađaju toksičan gas (supstance i smeše koje u kontaktu sa vodom ili vlažnim vazduhom oslobađaju gasove koji su klasifikovani kao akutno toksični, kategorija 1, 2 ili 3, kao što su aluminijum fosfid ili fosfor pentasulfid)

(402) 200

(403) Deo II

(404) Imenovane supstance

(405) Supstanca

(406) Granična količina

(407) (u tonama)

(408) 1a.

(409) Amonijum nitrat22

(410) 10 000

(411) 1b.

(412) Amonijum nitrat 23

(413) 5 000

(414) 1c.

(415) Amonijum nitrat 24

(416) 2 500

(417) 1d.

(418) Amonijum nitrat 25

(419) 50

(420) 2a.

(421) Kalijum nitrat26

(422) 10 000

(423) 2b.

(424) Kalijum nitrat 27

(425) 5 000

(426) 3.

(427) Arsen pentoksid, arsenatna (V) kiselina i/ili njene soli

(428) 2

(429) 4.

(430) Arsen trioksid, arsenitna (III) kiselina i/ili njene soli

(431) 0.1

(432) 5.

(433) Brom

(434) 100

(435) 6.

(436) Hlor

(437) 25

(438) 7.

(439) Jedinjenja nikla u obliku praha koja se mogu udahnuti: nikl monoksid, nikl dioksid, nikl sulfid, trinikl disulfid, dinikl trioksid

(440) 1

(441) 8.

(442) Etilenimin

(443) 20

(444) 9.

(445) Fluor

(446) 20

(447) 10.

(448) Formaldehid (koncentracija ≥ 90%)

(449) 50

(450) 11.

(451) Vodonik

(452) 50

(453) 12.

(454) Hlorovodonik (gas u tečnom stanju)

(455) 250

(456) 13.

(457) Alkili olova

(458) 50

(459) 14.

(460) Tečni zapaljivi gasovi, kategorija 1 ili 2 (uključujući tečni naftni gas) i prirodni gas28

(461) 200

(462) 15.

(463) Acetilen

(464) 50

(465) 16.

(466) Etilen oksid

(467) 50

(468) 17.

(469) Propilen oksid

(470) 50

(471) 18.

(472) Metanol

(473) 5 000

(474) 19.

(475) 4, 4′-metilen bis-(2-hloranilin) i/ili njegove soli, u obliku praha

(476) 0.01

(477) 20.

(478) Metil izocijanat

(479) 0.15

(480) 21.

(481) Kiseonik

(482) 2 000

(483) 22.

(484) Toluen diizocijanat (2,4-toluen diizocijanat i 2,6-toluen diizocijanat)

(485) 100

(486) 23.

(487) Karbonil dihlorid (fozgen)

(488) 0.75

(489) 24.

(490) Arsin (arsen trihidrid)

(491) 1

(492) 25.

(493) Fosfin (fosfor trihidrid)

(494) 1

(495) 26.

(496) Sumpor dihlorid

(497) 1

(498) 27.

(499) Sumpor trioksid

(500) 75

(501) 28.

(502) Polihlorovani dibenzofurani i polihlorovani dibenzodioksini (uključujući tetrahlordibenzodioksin (TCDD)), preračunati kao ekvivalent TCDD29

(503) 0.001

(504) 29.

(505) Sledeći karcinogeni ili smeše koje sadrže sledeće karcinogene u koncentracijama iznad 5% masenih: 4-Aminobifenil i/ili njegove soli, Benzotrihlorid, Benzidin i/ili njegove soli, Bis (hlormetil) etar, Hlormetil metil etar, 1,2-Dibrometan, Dietil sulfat, Dimetil sulfat, Dimetilkarbamoil hlorid, 1,2-Dibrom-3-hlorpropan, 1,2-Dimetilhidrazin, Dimetilnitrozamin, Heksametil fosfortriamid, Hidrazin, 2-Naftilamin i/ili soli, 4-Nitrodifenil i 1,3-Propansulton

(506) 2

(507) 30.

(508) Proizvodi od nafte i alternativna goriva:

(509) a) benzini i primarni benzini

(510) b) kerozini (uključujući goriva za mlazne avione)

(511) v) gasna ulja (uključujući dizel gorivo, lož ulja za domaćinstva i mešavine gasnih ulja)

(512) g) teška lož ulja;

(513) d) alternativna goriva koja služe za iste namene i sa sličnim svojstvima u pogledu zapaljivosti i opasnosti po životnu sredinu kao i proizvodi iz tačaka a) do g)

(514) 25 000

(515) 31.

(516) Amonijak, bezvodni

(517) 200

(518) 32.

(519) Bor trifluorid

(520) 20

(521) 33.

(522) Vodonik sulfid

(523) 20

(524) 34.

(525) Piperidin

(526) 200

(527) 35.

(528) Bis (2-dimetilaminoetil) (metil) amin

(529) 200

(530) 36.

(531) 3-(2-Etilheksiloksi) propilamin

(532) 200

(533) 37.

(534) Smeše natrijum hipohlorita klasifikovane kao opasnost po vodenu životnu sredinu, kategorija Akutno 1 [H400], koje sadrže < od 5% aktivnog hlora i nisu klasifikovane ni u jednu drugu kategoriju opasnosti u Delu I Aneksa I.30

(535) 500

(536) 38.

(537) Propilamin31

(538) 2 000

(539) 39.

(540) Terc-butil akrilat31

(541) 500

(542) 40.

(543) 2-Metil-3-butennitril31

(544) 2 000

(545) 41.

(546) Tetrahidro-3,5-dimetil-1,3,5,-tiadiazin-2-tion

(547) (Dazomet) (see note 21.)(dazomet)31

(548) 200

(549) 42.

(550) Metil akrilat31

(551) 2 000

(552) 43.

(553) 3-Metilpiridin31

(554) 2 000

(555) 44.

(556) Brom-3-hlorpropan31

(557) 2 000

(558) Napomene

(559) 1Kriterijumi u skladu sa Globalno harmonizovanim sistemom Ujedinjenih nacija – United Nations Globally Harmonized System (GHS) za klasifikaciju i obeležavanje hemikalija (ST/SG/AC.10/30/Rev.4). Strane treba da koriste ove kriterijume kada klasifikuju supstance ili smeše za potrebe Dela I ovog aneksa, osim ukoliko nisu u nacionalnom zakonodavstu usvojeni drugi pravno obavezujući kriterijumi. Smeše se tretiraju na isti način kao supstance, pod uslovom da su u okviru graničnih koncentracija propisanih prema njihovim svojstvima u skladu sa GHS, osim kada je posebno naveden procentualni sastav ili drugi opis.

(560) 2Prema kriterijumima iz poglavlja 3.1.2 i 3.1.3 GHS.

(561) 3Prema kriterijumima iz poglavlja 3.1.2 i 3.1.3 GHS.

(562) 4Supstance koje pripadaju klasi opasnosti akutna toksičnost, kategorija 3, peroralno, spadaju pod odeljak 2 akutna toksičnost u onim slučajevima kada se ne mogu klasifikovati niti na osnovu akutne inhalacione toksičnosti, niti na osnovu dermalne toksičnosti, na primer usled nedostatka ubedljivih podataka o inhalacionoj i dermalnoj toksičnosti.

(563) 5Supstance koje dovode do znatnih toksičnih efekata kod ljudi ili za koje se na osnovu eksperimenata na životinjama pretpostavlja da mogu da izazovu jake toksične efekte kod ljudi posle višekratne izloženosti. Dalje smernice su date na slici 3.8.1. i tabeli 3.8.1. dela 3 GHS.

(564) 6Ispitivanje eksplozivnih svojstava supstanci i smeša je neophodno samo ako se skrining procedurom, u skladu sa dodatkom 6, deo 3, Priručnika o metodama ispitivanja i kriterijumima, utvrdi da bi supstanca ili smeša mogla imati eksplozivna svojstva.

(565) 7Klasa opasnosti Eksplozivi obuhvata i eksplozivne proizvode. Ako je količina eksplozivne supstance ili smeše u eksplozivnom proizvodu poznata, ta količina se uzima u obzir za potrebe ove konvencije. Ako količina eksplozivne supstance ili smeše u proizvodu nije poznata, tada se, za potrebe ove konvencije, ceo proizvod tretira kao eksploziv.

(566) 8Ako su eksplozivi koji su klasifikovani u podklasu 1.4 raspakovani ili prepakovani, svrstavaju se pod odeljak 4 (Eksplozivi), osim ako se utvrdi da opasnost tog eksploziva još uvek odgovara podklasi 1.4, u skladu sa GHS.

(567) 9Prema kriterijumima iz poglavlja 2.2.2 GHS.

(568) 10Aerosoli su klasifikovani prema kriterijumima iz poglavlja 2.3 GHS i Priručnika o metodama ispitivanja i kriterijumima, Deo III, odeljak 31.

(569) 11Za korišćenje ovog odeljka mora se dokumentovati da aerosolni raspršivač ne sadrži zapaljivi gas, kategorija 1 ili 2, niti zapaljivu tečnost, kategorija 1.

(570) 12Prema kriterijumima iz poglavlja 2.4.2 GHS.

(571) 13Prema kriterijumima iz poglavlja 2.6.2 GHS.

(572) 14Tečnosti sa tačkom paljenja višom od 35 ⁰C mogu se smatrati nezapaljivim tečnostima za neke regulatorne svrhe (npr. transport), ukoliko su pri ispitivanju zapaljivosti prema L2, Deo III, odeljak 32 Priručnika o metodama ispitivanja i kriterijumima, dobijeni negativni rezultati. Ovo, međutim, ne važi pod uslovima kao što su visoka temperatura ili pritisak i stoga su takve tečnosti obuhvaćene ovim odeljkom.

(573) 15Prema kriterijumima iz poglavlja 2.6.2 GHS.

(574) 16Prema kriterijumima iz poglavlja 2.6.2 GHS.

(575) 17Prema kriterijumima iz poglavlja 2.8.2 i 2.15.2.2 GHS.

(576) 18Prema kriterijumima iz poglavlja 2.8.2 i 2.15.2.2 GHS.

(577) 19Prema kriterijumima iz poglavlja 4.1.2 GHS.

(578) 20Prema kriterijumima iz poglavlja 4.1.2 GHS.

(579) 21Prema kriterijumima iz poglavlja 2.12.2 GHS.

(580) 22Amonijum nitrat (10,000): đubriva koja imaju sposobnost samoodržive razgradnje. Ovo se primenjuje na složena/kombinovana đubriva na bazi amonijum-nitrata (složena/kombinovana đubriva sadrže amonijum nitrat sa fosfatom i/ili potašom), koja imaju sposobnost samoodržive razgradnje prema UN ispitivanju u koritu (vidi UN Priručnik o metodama ispitivanjima i kriterijumima, Deo III. pododeljak 38.2), i kod kojih je sadržaj azota koji potiče od amonijum-nitrata:

(581) a) između 15,75% i 24,5% masenih (udeo azota 15.75% i 24.5% masenih koji potiče od amonijum nitrata koji odgovara 45% i 70% amonijum nitratu) i koja ili ne sadrže više od 0,4% ukupno zapaljivih/organskih materija ili koja ispunjavaju zahteve odgovarajućeg testa otpornosti na detonaciju (npr., test sa čeličnom cevi od 4 inča);

(582) b) 15.75% masenih ili manje i neograničen sadržaj zapaljivih materija.

(583) 23Amonijum nitrat (5,000): kvaliteta kao za đubriva

(584) Ovo se primenjuje na prosta đubriva na bazi amonijum-nitrata i na složena/kombinovana đubriva na bazi amonijum-nitrata kod kojih je udeo azota koji potiče od amonijum nitrata:

(585) a) više od 24.5%, masenih, osim za smeše prostih đubriva na bazi amonijum-nitrata s dolomitom, krečnjakom i/ili kalcijum karbonatom od najmanje 90% čistoće,

(586) b) više od 15.75% masenih za smeše amonijum nitrata i amonijum sulfata,

(587) v) više od 28% (udeo azota 28% masenih koji potiče od amonijum-nitrata koji odgovara 80% amonijum-nitratu) masenih za smeše prostih đubriva na bazi amonijum-nitrata sa dolomitom, krečnjakom i/ili kalcijum karbonatom od najmanje 90% čistoće;

(588) i koja ispunjavaju zahteve odgovarajućeg testa otpornosti na detonaciju (npr., test sa čeličnom cevi od 4 inča);

(589) 24Amonijum nitrat (2,500): tehnički.

(590) Ovo se primenjuje na:

(591) a) amonijum nitrat i smeše amonijum nitrata kod kojih je udeo azota koji potiče od amonijum nitrata:

(592) (i) između 24,5% i 28%, masenih i koji ne sadrži više od 0,4% zapaljivih supstanci;

(593) (ii) više od 28%, masenih, i koji ne sadrži više od 0,2% zapaljivih supstanci;

(594) b) vodene rastvore amonijum-nitrata u kojima je koncentracija amonijum-nitrata veća od 80% masenih.

(595) 25Amonijum nitrat (50) („off-specs”) „nespecifični” materijal i đubriva koji ne ispunjavaju zahteve odgovarajućeg testa otpornosti na detonaciju (npr., test sa čeličnom cevi od 4 inča);

(596) Ovo se primenjuje na:

(597) a) materijal koji se odbacuje u toku proizvodnog procesa i na amonijum-nitrat i smeše amonijum nitrata, prosta đubriva na bazi amonijum-nitrata i složena đubriva na bazi amonijum-nitrata označena u napomenama 23 i 24, koje krajnji korisnici vraćaju ili su vratili proizvođaču, privremenom skladištu ili postrojenju za ponovnu obradu, reciklažu ili tretman radi bezbedne upotrebe, jer više ne ispunjavaju uslove iz napomena 23 i 24;

(598) b) đubriva iz napomene 22a) i napomene 23 koja ne ispunjavaju zahteve odgovarajućeg testa otpornosti na detonaciju (npr., test sa čeličnom cevi od 4 inča);

(599) 26Kalijum nitrat (10,000): kombinovana đubriva na bazi kalijum-nitrata (u kuglicama/granulama), koja imaju ista svojstva kao čist kalijum-nitrat.

(600) 27Kalijum nitrat (5000): kombinovana đubriva na bazi kalijum-nitrata (u obliku kristala), koja imaju ista opasna svojstva kao čist kalijum-nitrat.

(601) 28Prerađen biogas: za svrhu primene Konvencije prerađen biogas se može klasifikovati pod redni broj 14 Deo 2 Aneksa I, kada je obrađen u skladu sa važećim standardima za prečišćen i prerađen biogas, čime se obezbeđuje kvalitet koji je jednak kvalitetu prirodnog gasa, uključujući sadržaj metana, i koji sadrži maksimalno 1% kiseonika.

(602) 29Polihlorovani dibenzofurani i polihlorovani dibenzodioksini. Količine polihlorovanih dibenzofurana i polihlorovanih dibenzodioksina se izračunavaju koristeći sledeće faktore ekvivalentne toksičnosti za čoveka i sisare (TEF) Svetske zdravstvene organizacije (SZO) za dioksine i jedinjenja slična dioksinu, koji su ponovo preračunati 2005. godine:

(603) SZO 2005 TEF

(604) Dioksini

(605) TEF

(606) Furani

(607) TEF

(608) 2,3,7,8-TCDD

(609) 1

(610) 2,3,7,8-TCDF

(611) 0.1

(612) 1,2,3,7,8-PeCDD

(613) 1

(614) 2,3,4,7,8-PeCDF

(615) 0.3

(616) 1,2,3,4,7,8-HxCDD

(617) 0.1

(618) 1,2,3,7,8-PeCDF

(619) 0.03

(620) 1,2,3,6,7,8-HxCDD

(621) 0.1

(622) 1,2,3,4,7,8-HxCDF

(623) 0.1

(624) 1,2,3,7,8,9-HxCDD

(625) 0.1

(626) 1,2,3,7,8,9-HxCDF

(627) 0.1

(628) 1,2,3,4,6,7,8-HpCDD

(629) 0.01

(630) 2,3,4,6,7,8-HxCDF

(631) 0.1

(632) OCDD

(633) 0.0003

(634) 1,2,3,7,8,9-HxCDF

(635) 0.1

(636) 1,2,3,4,6,7,8-HpCDF

(637) 0.01

(638) 1,2,3,4,7,8,9-HpCDF

(639) 0.01

(640) OCDF

(641) 0.0003

(642) Skraćenice: Hx = heksa, Hp = hepta, O = okta, Pe = penta, T = tetra.

(643) Referenca: Martin Van den Berg i drugi, “2005 World Health Organization Reevaluation of Human and Mammalian Toxic Equivalency Factors for Dioxins and Dioxin-like Compounds”, Toxicological Sciences, vol. 93, No. 2 (October 2006), pp. 223–241.

(644) 30Pod uslovom da smeša u odsustvu natrijum-hipohlorita ne bi bila klasifikovana kao opasnost po vodenu životnu sredinu, kategorija Akutno 1.

(645) 31U slučajevima kada ova opasna supstanca spada u kategoriju 10 zapaljive tečnosti ili kategoriju 11 zapaljive tečnosti, za svrhu Konvencije primenjuje se najmanja granična količina.

Zakon o potvrđivanju Odluke 2014/2 o izmeni Aneksa I Konvencije o prekograničnim efektima industrijskih udesa

Član 1

Član 2

Član 3

Član 4